Please use this column with suppressor type ion chromatography system.
The United States Environmental Protection Agency (EPA) Method 300.1 specifies methods for anion analysis in drinking water. EPA Method 300.1 has two parts. Part A: analysis of common ions and Part B: analysis of inorganic disinfection byproducts. Both uses the same analysis methods.
This application shows the example analysis of artificial-drinking water (standards spiked) following the EPA Method 300.1. With an IC SI-37 4D, an anion analysis column, analysis of common anions and inorganic disinfection byproducts (oxyhalides) is completed within 30 minutes. Moreover, it is capable of providing high sensitivity analysis of oxyhalides.
Sample: 200 μL
(simulated drinking water containing EDA 50mg/L)
- 1.F- 1 mg/L
- 2.ClO2- 5 µg/L
- 3.BrO3- 5 µg/L
- 4.Cl- 50 mg/L
- 5.NO2- 5 µg/L
- 6.DCA- (Dichloroacetate) 1 mg/L
- 7.ClO3- 5 µg/L
- 8.Br- 5 µg/L
- 9.NO3- 10 mg/L
- 10.CO32- 25 mg/L
- 11.SO42- 50 mg/L
- 12.PO43- 0.2 mg/L
Substance | Range (μg/L) |
Linearity |
*RSD (%) | **MLD | ||
---|---|---|---|---|---|---|
Retention time |
Peak area |
Standard (μg/L) |
Calculated (μg/L) |
|||
ClO2- | 2 - 50 |
0.9994 |
0.26 | 1.05 | 2 | 0.12 |
BrO3- | 1 - 25 | 0.9995 | 0.19 | 0.97 | 2 | 0.28 |
ClO3- | 2 - 50 | 0.9995 | 0.08 | 1.10 | 2 | 0.34 |
Br- | 2 - 50 | 0.9994 | 0.14 | 1.60 | 2 | 0.36 |
*BrO3- 10 µg/L, ClO2-, ClO3-, Br- 20 µg/L each (n=7)
**Method detection limit
- Column
- :Shodex IC SI-90G (4.6 mm I.D. x 10 mm) + SI-37 4D (4.0 mm I.D. x 150 mm)
- Eluent
- :(Gradient) KOH aq.
10 mM (0 to 21 min), 45 mM (21.01 to 30 min)
(Eluent source : DionexTM EGC 500 KOH) - Flow rate
- :0.5 mL/min
- Detector
- :Suppressed conductivity
- Column temp.
- :30 ℃
Sample Name Index
- Bromate, BrO3-
- Bromide, Br-
- Carbonate, CO32-
- Chlorate, ClO3-
- Chloride, Cl-
- Chlorite, ClO2-
- Dichloroacetic acid, DCAA
- Fluoride, F-
- Hydrogencarbonate, HCO3-
- Nitrate, NO3-
- Nitrite, NO2-
- Phosphate tribasic, PO43-
- Sulfate, SO42-
Operation Manual / Certificate of Analysis
Operation Manuals and Certificate of Analysis / Inspection Certificate for the following products can be downloaded here.
Product Name Index
Applications
- Table of Anion Retention Time under Various Eluent Conditions (SI-90 4E)
- Effects of Sodium Carbonate Concentration on Retention Time (SI-90 4E)
- Effects of Sodium Bicarbonate Concentration on Retention Time (SI-90 4E)
- Effects of Temperature on Elution Time (SI-90 4E)
- Effects of Added Acetonitrile on the Retention Time (SI-90 4E)
- Effects of Column Temperature on Retention Time (SI-50 4E)
- Effects of Sodium Carbonate Concentration on Retention Time (SI-50 4E)
- Anion Standards (19) Rapid Analysis (SI-90 4E)
- Anion Standards (20) (Simultaneous Analysis of HS-, SO32-, SO42- and S2O32-) (SI-90 4E)
- Anion Standards (21) (Methanesulfonic Acid)
- High Sensitive Analysis of Anions (SI-90 4E)
- Anion Standards and Organic Acids (2) (SI-90 4E)
- Anion Standards and Organic Acids (3) (SI-50 4E)
- Mineral Water (2) (SI-90 4E)
- Sulfite in Wine (2) (SI-90 4E)
- Sodium Azide (2) (SI-90 4E)
- Sulfamic Acid (SI-90 4E)
- Sea Water (3) (SI-90 4E)
- Perchloric Acid (SI-90 4E)
- Analysis of Iodide Ion (SI-90 4E)
- Fluoroacetid Acids (SI-50 4E)
- Anion Analysis in Lithium Salts (3) (SI-90 4E)
- Analysis of Oxyhalides (SI-52 4E)
- Effects of Temperature on Retention Time (SI-52 4E)
- Calibration Curves for Oxyhalides (SI-52 4E)
- Analysis of Organic Acids and Oxyhalides (SI-52 4E)
- Analysis of Oxyhalides and Anions (SI-52 4E)
- Analysis of Oxyhalides and Anions in River Water (SI-52 4E)
- Analysis of Oxyhalides and Anions in Rain Water (SI-52 4E)
- Analysis of Oxyhalides and Anions in Tap Water (SI-52 4E)
- Iodic Acid (SI-52 4E)
- Separation of Phosphate, Phosphtite and Hypophosphite (SI-52 4E)
- Separation of Phosphate, Phosphtite and Hypophosphite (SI-90 4E)
- Analysis of Chloride According to Japanese Testing Methods for Fertilizers (SI-52 4E)
- Analysis of Sulfate According to Japanese Testing Methods for Fertilizers (SI-90 4E)
- Rapid Analysis of Oxyhalides and Anions (SI-35 4D) (1)
- Rapid Analysis of Oxyhalides and Anions (SI-35 4D) (2)
- Effects of Temperature on Retention Time (SI-35 4D)
- Analysis of Oxyhalides and Anions in Tap Water (SI-35 4D)
- Analysis of Organic Acids and Oxyhalides (SI-35 4D)
- Methanesulfonic Acid and Methanedisulfonic Acid (SI-35 4D)
- Calibration Curves (SI-35 4D)
- Effects of Injection Volume (SI-35 4D)
- Effects of Sample Concentration on Theoretical Plate Number (SI-35 4D)
- Analysis of Tricarboxylic Acids (SI-35 4D)
- Effects of Sodium Carbonate Concentration on Retention Time (SI-35 4D)
- Analysis of Sulfite in Disposable Wooden Chopsticks (SI-35 4D)
- Analysis of Alkyl Sulfonic Acids (2) (SI-35 4D)
- Rapid Analysis of Anion Standards (SI-35 2B)
- Calibration Curves (SI-35 2B)
- Effects of Temperature on Retention Time (SI-35 2B)
- Analysis of Anions (SI-36 4D)
- Effects of Potassium Hydroxide Concentration on Retention Time (SI-36 4D)
- Effects of Potassium Hydroxide Concentration on Retention Time (2) (SI-36 4D)
- Effects of Temperature on Retention Time (SI-36 4D)
- Simultaneous Analysis of Common Oxyhalides and Anions (SI-37 4D)