Alkyl sulfonic acids were analyzed using IC SI-35 4D, an anion analysis column for suppressor method. It was shown that the longer alkyl chains result with stronger the hydrophobic interaction between the packing material and the sample. With longer alkyl chains, retention time will increase.
Sample : 20 μL
1. Methanesulfonic acid 1 mg/L
2. Ethanesulfonic acid 2 mg/L
3. Propanesulfonic acid 4 mg/L
4. Butanesulfonic acid 4 mg/L
5. Pentanesulfonic acid 10 mg/L
6. Hexanesulfonic acid 20 mg/L
7. Toluenesulfonic acid 20 mg/L
Column : Shodex IC SI-35 4D (4.0 mm I.D. x 150 mm) Eluent : 2.0 mM Na2CO3 + 4.5 mM NaHCO3 aq. Flow rate : 0.6 mL/min Detector : Suppressed conductivity Column temp. : 55 °C
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Applications
- Table of Anion Retention Time under Various Eluent Conditions (SI-90 4E)
- Effects of Sodium Carbonate Concentration on Retention Time (SI-90 4E)
- Effects of Sodium Bicarbonate Concentration on Retention Time (SI-90 4E)
- Effects of Temperature on Elution Time (SI-90 4E)
- Effects of Added Acetonitrile on the Retention Time (SI-90 4E)
- Effects of Column Temperature on Retention Time (SI-50 4E)
- Effects of Sodium Carbonate Concentration on Retention Time (SI-50 4E)
- Anion Standards (19) Rapid Analysis (SI-90 4E)
- Anion Standards (20) (Simultaneous Analysis of HS-, SO32-, SO42- and S2O32-) (SI-90 4E)
- Anion Standards (21) (Methanesulfonic Acid)
- High Sensitive Analysis of Anions (SI-90 4E)
- Anion Standards and Organic Acids (2) (SI-90 4E)
- Anion Standards and Organic Acids (3) (SI-50 4E)
- Mineral Water (2) (SI-90 4E)
- Sulfite in Wine (2) (SI-90 4E)
- Sodium Azide (2) (SI-90 4E)
- Sulfamic Acid (SI-90 4E)
- Sea Water (3) (SI-90 4E)
- Perchloric Acid (SI-90 4E)
- Analysis of Iodide Ion (SI-90 4E)
- Fluoroacetid Acids (SI-50 4E)
- Anion Analysis in Lithium Salts (3) (SI-90 4E)
- Analysis of Oxyhalides (SI-52 4E)
- Effects of Temperature on Retention Time (SI-52 4E)
- Calibration Curves for Oxyhalides (SI-52 4E)
- Analysis of Organic Acids and Oxyhalides (SI-52 4E)
- Analysis of Oxyhalides and Anions (SI-52 4E)
- Analysis of Oxyhalides and Anions in River Water (SI-52 4E)
- Analysis of Oxyhalides and Anions in Rain Water (SI-52 4E)
- Analysis of Oxyhalides and Anions in Tap Water (SI-52 4E)
- Iodic Acid (SI-52 4E)
- Separation of Phosphate, Phosphtite and Hypophosphite (SI-52 4E)
- Separation of Phosphate, Phosphtite and Hypophosphite (SI-90 4E)
- Analysis of Chloride According to Japanese Testing Methods for Fertilizers (SI-52 4E)
- Analysis of Sulfate According to Japanese Testing Methods for Fertilizers (SI-90 4E)
- Rapid Analysis of Oxyhalides and Anions (SI-35 4D) (1)
- Rapid Analysis of Oxyhalides and Anions (SI-35 4D) (2)
- Effects of Temperature on Retention Time (SI-35 4D)
- Analysis of Oxyhalides and Anions in Tap Water (SI-35 4D)
- Analysis of Organic Acids and Oxyhalides (SI-35 4D)
- Methanesulfonic Acid and Methanedisulfonic Acid (SI-35 4D)
- Calibration Curves (SI-35 4D)
- Effects of Injection Volume (SI-35 4D)
- Effects of Sample Concentration on Theoretical Plate Number (SI-35 4D)
- Analysis of Tricarboxylic Acids (SI-35 4D)
- Effects of Sodium Carbonate Concentration on Retention Time (SI-35 4D)
- Analysis of Sulfite in Disposable Wooden Chopsticks (SI-35 4D)
- Rapid Analysis of Anion Standards (SI-35 2B)
- Calibration Curves (SI-35 2B)
- Effects of Temperature on Retention Time (SI-35 2B)
- Analysis of Anions (SI-36 4D)
- Effects of Potassium Hydroxide Concentration on Retention Time (SI-36 4D)
- Effects of Potassium Hydroxide Concentration on Retention Time (2) (SI-36 4D)
- Effects of Temperature on Retention Time (SI-36 4D)
- Simultaneous Analysis of Common Oxyhalides and Anions (SI-37 4D)
- Analysis of Oxyhalides in Artificial-Drinking Water According to EPA Method 300.1 (SI-37 4D)