Effects of Temperature on Retention Time (SI-52 4E)

Please use this column with suppressor type ion chromatography system.

In analysis using IC SI-52 4E, the retention times of some anions are very sensitive to the column temperature. An example is showed in the figure below. Usually bromide (Br-) and chlorate (ClO3-) are usually separated at 45 ℃.

Sample: 50 μL

  1. 1.F- (2 mg/L)
  2. 2.ClO2- (10 mg/L)
  3. 3.BrO3- (20 mg/L)
  4. 4.Cl- (3 mg/L)
  5. 5.NO2- (10 mg/L)
  6. 6.Br- (10 mg/L)
  7. 7.ClO3- (20 mg/L)
  8. 8DCA-, Dichloroacetate (5 mg/L)
  9. 9.NO3- (30 mg/L)
  10. 10.HPO42- (15 mg/L)
  11. 11.SO42- (40 mg/L)
Column
Shodex IC SI-52 4E (4.0 mm I.D. x 250 mm)
Eluent
3.6 mM Na2CO3 aq.
Flow rate
0.8 mL/min
Detector
Suppressed conductivity

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