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Analysis of Phosphate Referencing to National Ecological Environment Standards of China HJ 1362‑2024 (SI‑37 4D)

The National Ecological Environment Standards of China HJ 1362‑2024* “Determination of Phosphoric Acid Mist in Exhaust Gas from Stationary Sources by Ion Chromatography” specifies the use of a high‑capacity hydrophilic ion‑exchange column, which is packed with a base material such as polydivinylbenzene, ethylvinylbenzene, or polyvinyl alcohol, modified with quaternary ammonium groups having alkyl chains or alkyl alcohol chains. Using IC SI‑37 4D, an anion analysis column, a good linear calibration curve for phosphate and good separation of seven anions were obtained.
Note: The analytical conditions used in this application differ in part from those specified in the National Ecological Environment Standards of China HJ 1362‑2024.

*The version at the time of the application acquisition.

Sample: 25 µL

  1. 1.F- 1.0 mg/L
  2. 2.Cl- 3.0 mg/L
  3. 3.NO2- 3.0 mg/L
  4. 4.SO42- 5.0 mg/L
  5. 5.Br- 5.0 mg/L
  6. 6.NO3- 5.0 mg/L
  7. 7.PO43- 5.0 mg/L
Chromatogram of anions

Sample: 25 µL

  1. 7.PO43- 5.0 mg/L
Chromatogram of phosphate

 

Calibration curve fot phosphate
Column
Shodex IC SI-37 4D (4.0 mm I.D. x 150 mm)
Eluent
23 mM KOH aq.
Flow rate
0.7 mL/min
Detector
Suppressed conductivity
Column temp.
30 ℃

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