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Analysis of Nitrate According to National Ecological Environment Standards of China HJ 1361‑2024 (SI‑90 4E)

The National Ecological Environment Standards of China HJ 1361‑2024* “Determination of Nitric Acid Mist in Exhaust Gas from Stationary Sources by Ion Chromatography” specifies the use of a high‑capacity hydrophilic ion‑exchange column, which is packed with a base material such as polydivinylbenzene, ethylvinylbenzene, or polyvinyl alcohol, modified with quaternary ammonium groups having alkyl chains or alkyl alcohol chains. Using IC SI-90 4E, an anion analysis column, a good linear calibration curve for nitrate and good separation of seven anions were obtained.
In contrast to the official method, sulfate eluted last under the conditions used in this application.

*The version at the time of the application acquisition.

Sample: 25 µL

  1. 1.F- 1.0 mg/L
  2. 2.Cl- 3.0 mg/L
  3. 3.NO2- 3.0 mg/L
  4. 4.Br- 5.0 mg/L
  5. 5.NO3- 5.0 mg/L
  6. 6.HPO42- 5.0 mg/L
  7. 7.SO42- 5.0 mg/L
Chromatogram of anions

Sample: 25 µL

  1. 5.NO3- 5.0 mg/L
Chromatogram of nitrate

 

Calibration curve for nitrate
Column
Shodex IC SI-90 4E (4.0 mm I.D. x 250 mm)
Eluent
3.2 mM Na2CO3 + 1.0 mM NaHCO3 aq.
Flow rate
0.7 mL/min
Detector
Suppressed conductivity
Column temp.
30 ℃

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