Analysis of TMAH and Cations (YS-50)

Tetramethylammonium hydroxide (TMAH) is widely used as a photoresist developer in semiconductor manufacturing processes. In photoresist developer solutions, trace levels of cations such as Na+, NH4+, and K+ must be carefully controlled. In this application, standard solutions of TMAH, Na+, NH4+, and K+ were analyzed using a cation chromatography column, IC YS-50. There was a good linearity in the 1 to 100 mg/L range for TMAH.

Sample: 10 µL

  1. 1.Na+ 2 mg/L
  2. 2.NH4+ 2mg/L
  3. 3.K+ 2 mg/L
  4. 4.Tetramethylammonium hydroxide (TMAH) 50 mg/L
Chromatogram of TMAH

 

Calibration curve for TMAH
Column
Shodex IC YS-50 (4.6 mm I.D. x 125 mm)
Eluent
4 mM Methanesulfonic acid aq.
Flow rate
1.0 mL/min
Detector
Non-suppressed conductivity
Column temp.
40 ℃

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