Analysis of Residual ε-Caprolactam in Nylon 6 (ODP-50 4D)

ε-caprolactam, a residual monomer in nylon 6, was analyzed using Asahipak ODP-50 4D, a reversed-phase chromatography column. Analysis of ε-caprolactam can be performed without an influence from extract contaminants.

Sample pretreatment

  • Add 10 mL of pure water to 0.5 g of nylon 6 pellets. Seal and heat at 100 ℃ for 2 hours.
  • Once the mixture is cooled to room temperature, filter through a 0.5μm filter. Use the filtrate as a test sample.

Sample: 10 μL

  1. 1.ε-Caprolactam
ε-Caprolactam_chromatogram
Column
Shodex Asahipak ODP-50 4D (4.6 mm I.D x 150 mm)
Eluent
H2O/CH3CN=80/20
Flow rate
0.7 mL/min
Detector
UV (210 nm)
Column temp.
40 ℃

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