使用微柱RSpak DE-213进行高尔夫球场用农药的LC/MS分析,可以分析GC,GC/MS无法分析的对热不稳定的、难挥发性的农药。
Sample : 20 ng each, 20 μL
1. Asulam
2. 2-(4-Chloro-2-methylphenoxy)propanoic acid, MCPP
3. Thiuram
4. Bensulide, SAP
5. Iprodione
6. Pencycuron
(HPLC) Instrument : Agilent 1100 Column : Shodex RSpak DE-213 (2.0 mm I.D. x 150 mm) Eluent : (A): 50 mM CH3COONH4 aq. (B): CH3CN 0 min to 10 min, (B)10 % to (B)100 % Flow rate : 0.2 mL/min Column temp. : 40 ℃ (MS) Instrument : Agilent 1100MSD Mass range : 105-500 (m/z) Ionization : Electrospray Polarity : Positive, Negative Fragmentor : 60 V Nebulizer : N2 (50psi) Drying gas : N2 (12 L/min, 350 ℃)